In this work, we discuss new opportunities in solvent-free synthesis including newly researched vapor deposition and mechanochemical methods, as well as other potential insights within this direction. Breakthroughs on solvent toxicity minimization or even solvent exemption can pave a new roadmap to the future development of perovskite-based applications. However, commonly used solvents are of high-cost, environmentally unfriendliness, high treatment complexity, and low post-processing convenience. Traditional synthesis of halide perovskites follows a wet chemistry route, that is, dissolving precipitation through a solution medium. Construction of these frontier applications will fundamentally require a benign material platform of great sample quality but easy accessibility. Whether you will die in the dungeons or rise to victory against the Baron and his hellspawn is ultimately up to you.Halide perovskites have been extensively researched in the past decade and explored in fields stepping out from photovoltaics towards photothermal and thermoelectric energy conversion, light-emission, high-energy electromagnetic radiation detection, memristors/artificial synapses, ferroelectricity, etc. The whole town's been trapped in his massive dungeon for decades and now it's up to a single hero or a group of adventurers to confront him in his hellish lair and destroy him forever. He enslaved Hamlet's people and now he's an awful undead lich. That is, it was until the heinous Baron Herx came along and claimed the whole thing as his Barony.
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